| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1312893 | Inorganica Chimica Acta | 2006 | 5 Pages |
Two lanthanide-decorated polyoxometalates K[Ln2(α-SiW11O39)(H2O)11] (Ln = La, Ce) have been successfully synthesized and characterized with single-crystal X-ray diffraction, IR spectroscopy and thermogravimetric analysis. The two compounds have analogy structures, which consist of one-dimensional chains based on [α-SiW11O39]8− building blocks. The chains are further connected to a two-dimensional layer by potassium ions. The magnetic studies of compound 1 demonstrate a ferromagnetic interaction in 1.
Graphical abstractTwo new lanthanide-decorated polyoxometalates K[Ln2(α-SiW11O39)(H2O)11] (Ln = La, Ce) have been synthesized and structurally characterized, which consist of one-dimensional chains based on [α-SiW11O39]8− building blocks. The chains are further connected to a two-dimensional layer by potassium ions.Figure optionsDownload full-size imageDownload as PowerPoint slide
