Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization

Two lanthanide(III) complexes with l-glutamate ligands [{Ln2(l-Glu)2(H2O)8} · 4(ClO4) · 2.5H2O]n (Ln = Gd (1), Eu (2)) have been prepared and characterized by single-crystal X-ray diffraction. The compounds are isomorphous with infinite cationic 2D layers stacked together by secondary bonds. The building blocks are slightly different non-centrosymmetric dinuclear units placed in alternating layers, the resulting structures thus containing four non-equivalent Ln metal sites. The dinuclear units contain a fourfold bridge, two in the η1:η1:μ2 and two in the η2:η1:μ2 modes, from two α- and two γ-carboxylates of four different l-Glu residues, respectively.

Graphical abstractGadolinium(III) and europium(III) complexes with l-glutamate ligands have been prepared and their crystal structures solved by single crystal X-ray diffraction. The isomorphous complexes [Ln2 (l-Glu)2(H2O)8] · 4(ClO4) · 2.5H2O(Ln = Gd (1), Eu (2)) consist of infinite cationic layer arrangements stacked together by secondary bonds. The building blocks are non-centrosymmetric dimers slightly different in two successive layers, the resulting structures thus containing four non-equivalent metal sites.Figure optionsDownload full-size imageDownload as PowerPoint slide