Article ID Journal Published Year Pages File Type
1312910 Inorganica Chimica Acta 2006 7 Pages PDF
Abstract
Two novel ion-pair complexes, [RBzIQl]+[Ni(mnt)2]− (mnt2− = maleonitriledithiolate, [RBzIQl]+ = 4-R-benzylisoquinolinium; R = H (1), Cl (2)) have been characterized structurally and magnetically. The anions and cations in 1 form 1D column of alternating between cations and anions, while those of 2 stack into well-segregated columns and the Ni(III) ions form a 1D uniform zigzag chain. The former shows antiferromagnetic coupling behavior, and the latter exhibits antiferromagnetic interaction in the high-temperature phase (HT) and spin gap in the low-temperature phase (LT).
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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