Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1312921 | Inorganica Chimica Acta | 2006 | 12 Pages |
Abstract
The reactivity of the silylated sterically hindered thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2] was examined with transition metal complexes of group 10. A series of palladium(II) and platinum(II) complexes were obtained. The formulation of these complexes was dependent of the stoichiometry and relative size of the metal and the thiolate. Analogous reactions with nickel complexes afforded disulfides products of the oxidation of the thiols.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Viviana Cordero-Pensado, Valente Gómez-BenÃtez, Simón Hernández-Ortega, Rubén A. Toscano, David Morales-Morales,