Article ID Journal Published Year Pages File Type
1312984 Inorganica Chimica Acta 2006 6 Pages PDF
Abstract
Reaction between OsCl(NO)(PPh3)3 and 3,3-diphenylcyclopropene leads to the stable π-adduct, Os(η2-3,3-diphenylcyclopropene)Cl(NO)(PPh3)2, which in turn undergoes a ring-opening reaction with HCl to form the diphenylallyl complex, Os(CH2CHCPh2)Cl2(NO)(PPh3)2.
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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Synthesis and structure of Os(η2-3,3-diphenylcyclopropene)Cl(NO)(PPh3)2 and the ring-opening reactions of the π-bound cyclopropene with acids
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