| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1313004 | Inorganica Chimica Acta | 2006 | 9 Pages |
Abstract
Fluorous palladium complexes based on the chiral ligand α-methyl-N,N-dimethylbenzylamine (TMBA) are described. Cyclo-palladation by treatment with Pd(OAc)2/LiCl gave the dimeric arylpalladium(II) complexes, which were converted into monomeric adducts by complexation with pyridine or triphenylphosphine. The fluorophilicty of the different compounds as determined in perfluoromethylcyclohexane/n-octane as well as the crystal molecular structure of the triphenylphosphine complex are discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Henk Kleijn, Arjan W. Kleij, Jeroen J.M. de Pater, Martin Lutz, Anthony L. Spek, Johann T.B.H. Jastrzebski, Berth-Jan Deelman, Gerard van Koten,