| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1313053 | Inorganica Chimica Acta | 2006 | 5 Pages |
Abstract
We have prepared the oxo-bridged dimer [Ru(bpb)(NO]2(μ-O) in 60% isolated yield from the reaction of the known Ru(bpb)(NO)Cl with silver nitrite. The compound exhibits a υNO of 1758 cm−1 (KBr pellet). The crystal structure reveals a linear ON–Ru–O–Ru–NO fragment with the oxo atom serving as an inversion center in the molecule. The redox behavior in DMF is characterized by a reversible reduction followed by a second but irreversible reduction in this solvent.
Graphical abstractThe oxo-bridged dimer [Ru(bpb)(NO]2(μ-O) has been prepared in 60% isolated yield, and has been characterized by infrared spectroscopy, X-ray crystallography, and electrochemistry.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Zaki N. Zahran, Douglas R. Powell, George B. Richter-Addo,