Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1313073 | Inorganica Chimica Acta | 2006 | 9 Pages |
Abstract
Reactions of RSnCl3 (R = Et & nBu) with internally functionalized oximes in anhydrous benzene afforded non-ionic fibrous complexes of the general formula RSnCl3 · nHONC(Râ²)Ar [R = Et & Bu; Râ²Â = H, Me n = 1 & 2; Ar = 2-NC5H4, 2-OC4H3]. The crystal and molecular structures of one of the adducts nBuSnCl3 · HONC(Me)Py-2 · C6H5Me and of a trinuclear hydroxo bridged stannoxane {nBuSnCl2 (ONC(Me)Py-2)OH}2 SnnBuCl · 0.5 HONC(Me)Py-2, obtained on hydrolysis of nBuSnCl3 · 2HONC(Me)Py-2, revealed a distorted octahedral environment around tin with the participation of both nitrogen atoms (ring as well as oxime nitrogen atom of the same ligand moiety) in coordination.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Vinita Sharma, Sangeeta Agrawal, Rakesh Bohra, Raju Ratnani, John E. Drake, Ann L. Bingham, Michael B. Hursthouse, Mark E. Light,