| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1313084 | Inorganica Chimica Acta | 2006 | 4 Pages |
Dinitrato(ethylenediamine)palladium(II) has been crystallized from aqueous solution following treatment of enPdCl2 with AgNO3. The en ligand is chelating and the two nitrate ligands bind monofunctionally. When brought in water, the nitrates are immediately replaced by water ligands, thus providing a convenient source of highly reactive [enPd(H2O)2]2+. 1H NMR spectra of the title compound in dimethylformamide and acetonitrile indicate proton exchange between NH2 groups of en ligands.
Graphical abstractDinitrato(ethylenediamine)palladium(II) is a convenient source of enPdII for reactions carried out in water. Its preparation, X-ray crystal structure determination, and 1H NMR spectra are reported.Figure optionsDownload full-size imageDownload as PowerPoint slide
