| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1313088 | Inorganica Chimica Acta | 2006 | 6 Pages |
Abstract
The novel zwitterionic complexes mer-[ReOCl3(Hhp)(PPh3)] and mer-[ReOBr3(Hhp)(PPh3)] (Hhp = 2-hydroxypyridine), whose X-ray crystal structures were determined, adopt a distorted octahedral coordination for the rhenium(V) center. The monodentate Hhp ligands coordinate in their protonated neutral form via their exocyclic oxygen atoms, which is novel for rhenium coordination compounds with this type of ligand.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Elizeu J. de Souza, Victor M. Deflon, André G. de A. Fernandes, Sebastião S. Lemos, Adelheid Hagenbach, Ulrich Abram,