Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1313139 | Inorganica Chimica Acta | 2006 | 7 Pages |
Abstract
Reaction of [Pt2(μ-S)2(PPh3)4] with Bi(S2CNEt2)3 or Bi(S2COEt)3 in methanol gives the monocationic adducts [Pt2(μ-S)2(PPh3)4Bi(S2CNEt2)2]+ and [Pt2(μ-S)2(PPh3)4Bi(S2COEt)2]+; the complexes have been studied by positive-ion electrospray mass spectrometry, and an X-ray structure determination carried out on [Pt2(μ-S)2(PPh3)4Bi(S2CNEt2)2]PF6, revealing a six coordinate, approximately nido-pentagonal bipyramidal bismuth centre.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
William Henderson, Brian K. Nicholson, Hao Zhang, T.S. Andy Hor,