Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1313179 | Inorganica Chimica Acta | 2005 | 7 Pages |
Abstract
Two novel ion-pair complexes, 1-(4â²-bromo-2â²-fluorobenzyl)isoquinolinium-bis(maleonitriledithiolato)nickel(III), [BrFBzIQl] · Ni(mnt)2 · 0.5MeCN (1) and 1-(4â²-bromo-2â²-flouorobenzyl)-quinolinium-bis(maleonitriledithiolato)nickel(III), [BrFBzQl] · Ni(mnt)2 (2), have been characterized structurally and magnetically. The changes of coupling constants were observed in these two complexes at 85 K for 1 and 70 K for 2. It is interesting that 1 undergoes a transition from antiferromagnetic to ferromagnetic phase and 2 does counter to that of 1.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Chunlin Ni, Yizhi Li, Dongbin Dang, You Song, Zhaoping Ni, Qingjin Meng,