Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1313195 | Inorganica Chimica Acta | 2005 | 4 Pages |
Abstract
The reactions of aminobis(phosphines), Ph2PN(R)PPh2 (R = H, Me, Et, nPr, nBu, Ph), with Me2Pt(COD) led to the formation of four-membered metallacycles in good yield. The enthalpies of the ligand substitution reactions are measured by the anaerobic solution calorimetry in THF at 30 °C.
Graphical abstractThe reactions of aminobis(phosphines), with PtMe2(COD) led to the formation of chelate complexes, [PtMe2{Ph2PN(R)PPh2-κP,κP}]. The enthalpies of the substitution reactions were measured by the solution calorimetry.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Maravanji S. Balakrishna, Srinivasan Priya, William Sommer, Steven P. Nolan,