| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1313196 | Inorganica Chimica Acta | 2005 | 6 Pages |
Abstract
CR1R2OH, Ri = CH3 or H, react with the complex [CoIII(NH3)5CN]2+ to form an observable intermediate probably via bonding to the nitrogen of the cyanide. This intermediate isomerizes to form a second intermediate. The second intermediate decomposes into Co2+(aq), 5NH4+, CNâ and R1R2CO.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Formation of an observable intermediate during the reduction of [Co(III)(NH3)5CN]2+ by CR1R2(OH) radicals](/preview/png/1313196.png "First Page Preview: Formation of an observable intermediate during the reduction of [Co(III)(NH3)5CN]2+ by CR1R2(OH) radicals")
Authors
Ronit Herscu-Kluska, Haim Cohen, Dan Meyerstein,