Article ID Journal Published Year Pages File Type
1313209 Inorganica Chimica Acta 2005 8 Pages PDF
Abstract
The kinetics of the cis-to-planar interconversion of cis-diaqua(1,4,7,11-tetraazacyclotetradecane)Ni(II) perchlorate has been performed spectrophotometrically in basic aqueous solution. The first order rate law is followed. And the large ΔH≠ (61.7 kJ mol−1) and the large positive ΔS≠ (30.2 J K−1 mol−1) values strongly support a free-base-catalyzed mechanism for this reaction.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
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Kinetics of the cis-to-planar interconversion of cis-diaqua(1,4,7,11-tetraazacyclotetradecane)nickel(II) ion
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