Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1313641 | Journal of Fluorine Chemistry | 2016 | 6 Pages |
Abstract
Fenton reagent-catalyzed trifluoromethylation of enamines of ethyl 3-oxocarboxylates with CF3I followed by acid hydrolysis provided 3-oxo-2-(trifluoromethyl)carboxylates in 64-94% yields, which converted (2,2,2-trifluoroethyl)ketones in satisfactory yields by hydrolysis and successive decarboxylation.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yuhki Ohtsuka, Daisuke Uraguchi, Kyoko Yamamoto, Kenji Tokuhisa, Tetsu Yamakawa,