Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1313693 | Journal of Fluorine Chemistry | 2012 | 4 Pages |
Abstract
5-[Hydroxy(aryl/alkylamino)methylene]-2,2-dimethyl-1,3-dioxane-4,6-diones react with BF3·Et2O in mild conditions leading to the formation of boron difluoride complexes of carbamoyl Meldrum's acids. The X-ray structure has been obtained for one representative complex. The obtained new compounds are air and moisture stable at standard ambient conditions and easily isolable.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The new type of carbamoyl Meldrum's acids derivatives have been revealed. ► The structure of the new compounds were confirmed with X-ray crystallography. ► Prepared complexes are stable and easily isolable. ► Other derivatives of Meldrum's acids was examined.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Natalia Pawelska, Łukasz Ponikiewski, Sławomir Makowiec,