| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1313730 | Journal of Fluorine Chemistry | 2015 | 6 Pages |
Abstract
•Anomeric-selectivity data was obtained for the 6-F and 6-OBn glucose donor scaffolds.•At low temperatures the 6-OBn substitution increasingly outperformed the 6-F motif.•Prevalence of the β-anomer was found with iPrOH as glycosyl acceptor.•Eyring plots were constructed to derive the thermodynamic parametersΔΔH‡ andΔΔS‡.•ΔΔS‡(6-F) ≈ ΔΔS‡(6-OBn) indicated similar rigidification of the β-transition states.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nico Santschi, Nuria Aiguabella, Vanessa Lewe, Ryan Gilmour,