Article ID Journal Published Year Pages File Type
1313730 Journal of Fluorine Chemistry 2015 6 Pages PDF
Abstract

•Anomeric-selectivity data was obtained for the 6-F and 6-OBn glucose donor scaffolds.•At low temperatures the 6-OBn substitution increasingly outperformed the 6-F motif.•Prevalence of the β-anomer was found with iPrOH as glycosyl acceptor.•Eyring plots were constructed to derive the thermodynamic parametersΔΔH‡ andΔΔS‡.•ΔΔS‡(6-F) ≈ ΔΔS‡(6-OBn) indicated similar rigidification of the β-transition states.

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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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