Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1313861 | Journal of Fluorine Chemistry | 2013 | 4 Pages |
Abstract
A fluorous bis(oxazolines) was synthesized and tested as ligand in Cu-catalyzed Henry reaction of nitromethane to different aldehydes. The process was carried out in ethanol, and the corresponding β-nitroalcohols were obtained in 61-75% yield with enantioselectivities up to 99%. Furthermore, the fluorous ligand can be easily recovered and reused without significant loss in its activity.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Tao Deng, Chun Cai,