| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1313943 | Journal of Fluorine Chemistry | 2015 | 4 Pages |
Abstract
•Reactions of fluorinated organozinc reagents.•Reactions of β-nitrostyrenes.•Copper-catalyzed nitro group substitution.
A novel reactivity pattern of gem-difluorinated organozincs in copper(I) catalyzed reaction with β-nitrostyrenes is described. The reaction proceeds not as conjugate addition, but as nitro group substitution furnishing alkenes as single E-isomers in moderate yields.
Graphical abstractNitro group substitution in copper-catalyzed reaction of gem-difluorinated organozinc reagents with β-nitrostyrenes is described.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nikolay S. Kondratyev, Vitalij V. Levin, Artem A. Zemtsov, Marina I. Struchkova, Alexander D. Dilman,