| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314100 | Journal of Fluorine Chemistry | 2012 | 8 Pages |
Abstract
The synthesis of fluorosulfones by alkylation of fluoroacetate derivatives is reported. Their decarboxylation reaction under Krapcho conditions is a convenient process to prepare fluorosulfones as reagents for fluoroalkene synthesis.
Graphical abstractKrapcho decarboxylation of benzothiazolylsulfones opens up an improved route for the synthesis of fluorosulfones as Julia–Kocienski reagents.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Alkylation of heterocyclic fluorosulfones. ► Decarboxylation of fluoroester. ► Synthesis of fluorosulfones.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Florent Larnaud, Emmanuel Pfund, Bruno Linclau, Thierry Lequeux,