Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1314178 | Journal of Fluorine Chemistry | 2011 | 6 Pages |
This paper reports both on a general multistep synthesis of a wide family of aryl substituted perfluorosulfonimides and on a preliminary electrochemical investigation of two lithium salts hosted by a poly(oxyethylene) homopolymer. Both salts have a cationic transference number more than twice that of LiTFSI. Additionally, one of these salts exhibits markedly higher cationic conductivities than POE/LiTFSI electrolytes. These preliminary data are very encouraging as, thanks to the aryl moiety, a wide variety of salts can be considered in order to still improve the performances of polymer electrolytes.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Multistep synthesis allowing wide variety of salts to be prepared. ► High conductivity of PEO electrolytes. ► Wide electrochemical stability window.