| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314232 | Journal of Fluorine Chemistry | 2014 | 7 Pages |
Abstract
- New hydroxylammonium fluorometallates with the formulas (NH3OH)2MnF4 and (NH3OH)3ScF6, were prepared in aqueous HF.
- (NH3OH)2MnF4 crystallizes monoclinic, P21/c, the structure consisting of [MnF42â]n anionic layers perpendicular to a axis.
- (NH3OH)3ScF6 crystallizes trigonal, R3c, with isolated ScF6 octahedra, surrounded by hydroxylammonium cations.
- Both compounds decompose during thermal analysis in several steps, yielding corresponding fluorides (MnF2 and ScF3).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Matjaž Kristl, Brina Dojer, NuÅ¡a Hojnik, Amalija GolobiÄ,