Article ID Journal Published Year Pages File Type
1314392 Journal of Fluorine Chemistry 2011 7 Pages PDF
Abstract
► New dimeric anions [MnIII2F8(H2O)2]2− and [MnIII2F8(H2PO4)2]4− with double F-bridges. ► Strong asymmetry of the Mn-F-Mn bridges due to Jahn-Teller distortion. ► trans-Equatorial position of the oxo ligands by Jahn-Teller stabilization.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Jahn-Teller-distorted dimeric anions in (cat)[Mn2F8(H2O)2]·2H2O (cat = pipzH2, dabcoH2) and (dabcoH2)2[Mn2F8(H2PO4)2]
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