| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314395 | Journal of Fluorine Chemistry | 2011 | 7 Pages |
A series of highly fluorinated compounds bearing two or four perfluoroalkyl (RF) chains, with a flexible or rigid core have been synthesized. Radical additions, nucleophilic addition or condensation reactions were implemented for these synthesis, using perfluoroalkylated iodides and alcohols and various type of substrates: bis(allylic) derivatives, epichlorhydrin, diacid derivatives. All compounds contain an unsaturated moiety (vinyl, allyl or internal double bond) to be grafted on silicone materials by a catalyzed hydrosilylation reaction.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Synthesis of unsaturated bis- and tetra(perfluorooctyl) compounds for hydrosilylation. ► Bis- and tetra(perfluorooctyl) grafts synthesized from epichlorhydrin and diacids scaffolds. ► Grafting of highly fluorinated compounds on silicone materials for textile treatment.
