Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1314418 | Journal of Fluorine Chemistry | 2013 | 4 Pages |
Abstract
•New N,N-disubstituted aminodifluorosulfinium tetrafluoroborate salts are reported.•Their reactivity/selectivity in deoxofluorination reactions was compared.•The nature of the substituent on the amino moiety impacts the reactivity/selectivity.
The synthesis of N,N-disubstituted aminodifluorosulfinium tetrafluoroborate salts is reported, and their behavior as deoxofluorinating agent was evaluated. The deoxofluorination reactions were performed using a primary alcohol, a secondary alcohol and a ketone. Results show that subtle modification of the structure of the reagents can noticeably affect the reactivity and the selectivity in deoxofluorination reactions.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Olivier Mahé, Alexandre L’Heureux, Michel Couturier, Christopher Bennett, Simon Clayton, David Tovell, Francis Beaulieu, Jean-François Paquin,