New ionic liquids with the bis[bis(pentafluoroethyl)phosphinyl]imide anion, [(C2F5)2P(O)]2N−—Synthesis and characterization

A new series of low melting and hydrophobic ionic liquids (ILs) containing the bis[bis(pentafluoroethyl)phosphinyl]imide anion, [(C2F5)2P(O)]2N− (FPI), and ammonium, phosphonium, imidazolium, pyridinium or pyrrolidinium cations were prepared and characterized. Their density, viscosity, melting point, glass transition temperature, decomposition temperature and conductivity are discussed. Many of these ionic liquids are liquids at room temperature with melting points below 15 °C, viscosities below 110 mm2 s−1 and thermal stabilities above 300 °C.

Graphical abstractIonic liquids with the bis[bis(pentafluoroethyl)phosphinyl]imide – anion are synthesized via metathesis reactions in aqueous solution.Figure optionsDownload full-size imageDownload as PowerPoint slide