| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314466 | Journal of Fluorine Chemistry | 2010 | 5 Pages |
Abstract
CF3CFBr2 was employed in catalytic olefination reactions of aromatic aldehydes. In situ prepared hydrazones of aldehydes were transformed to β-fluoro-β-(trifluoromethyl)styrenes by reaction with CF3CFBr2 under CuCl catalysis. Based on this reaction, a novel stereoselective approach towards β-fluoro-β-(trifluoromethyl)styrenes was elaborated. Nucleophilic vinylic substitution of fluorine by secondary amines, thiolates and alkoxides in β-fluoro-β-(trifluoromethyl)styrenes was also tested.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Aleksey A. Goldberg, Vasiliy M. Muzalevskiy, Aleksey V. Shastin, Elisabeth S. Balenkova, Valentine G. Nenajdenko,