| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314474 | Journal of Fluorine Chemistry | 2010 | 7 Pages |
Abstract
Chromatographic separation of fluorinated amino acids and oligopeptides from their non-fluorinated counterparts were investigated at various temperatures using both hydrocarbon and fluorocarbon eluents and columns. The results show that fluorinated amino acids and oligopeptides demonstrate preference toward fluorocarbon eluents and fluorocarbon column compared to their non-fluorinated counterparts.
Keywords
RPLCFMOChexafluoroisopropanolTFTHOBtHFIPtert-butylTFECysTFAISPPHEtrifluoroethanoltBuEtOHDCMDMFDICTrpTRTnuclear magnetic resonanceN-hydroxybenzotriazoleN,N′-diisopropylcarbodiimideN,N-dimethylformamideN,N-diisopropylethylamineEthanolTrifluoroacetic acidFluorinated amino acidsIsopropanolTryptophanNMRChemical shifttritylTyrTyrosineDichloromethaneRetention timeCysteineMass spectrometryfluorenylmethoxycarbonylFluorophilicityPhenylalanineLysineLYSNleDIPEAnorleucineNvanorvalineMolecular weightReversed-phase liquid chromatographyhigh-performance liquid chromatographyHPLC
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nu Xiao, Y. Bruce Yu,