Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1314493 | Journal of Fluorine Chemistry | 2013 | 4 Pages |
Abstract
⺠Fluorination of functionalized adamantanes was performed with BrF3. ⺠Three to two fluorine atoms were selectively introduced to their tert-carbons. ⺠From methyl adamantane-1-carboxylate, methyl 3,5,7-trifluoroadamantane-1-carboxylate was selectively formed. ⺠Unexpected reactions, such as fluorination of carbonyl group, also occurred.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Toru Shishimi, Shoji Hara,