| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314562 | Journal of Fluorine Chemistry | 2012 | 4 Pages |
Abstract
Trisubstituted (2-fluoroalkenyl)iodonium salts were prepared E- or Z-selectively by the reaction of (fluoroalkenyl)iodonium ylides generated from (fluoroalkenyl)iodonium salts with aldehydes.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The reaction of (fluoroalkenyl)iodonium salt with LDA gave (fluoroalkenyl)iodonium ylide. ► Trisubstituted (fluoroalkenyl)iodonium salt was formed by the reaction of the (fluoroalkenyl)iodonium ylide with aldehyde. ► The reaction proceeds stereoselectively without losing its original stereochemistry. ► Both (E)- and (Z)-isomers can be prepared selectively.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Satoshi Shimobaba, Ryuhei Tahara, Shoji Hara,