Article ID Journal Published Year Pages File Type
1314586 Journal of Fluorine Chemistry 2013 8 Pages PDF
Abstract

•A direct Pd-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates to afford fluorinated biaryls has been developed.•This reaction proceeds under mild conditions for the CH bond activation.•A wide range of important functional groups are compatible with this reaction.

The direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates gave the desired products of fluorinated biaryls in good to excellent yields. A diverse set of important functional groups including methoxy, aldehyde, ester, nitro and halide can be well tolerated in the protocol.

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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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