| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314725 | Journal of Fluorine Chemistry | 2012 | 7 Pages |
A convenient synthesis of N,N-bis(trifluoromethyl)anilines by means of dediazotation reactions of previously unknown aryldiazoniumbis(trifluoromethyl)imides in the presence of CuI salts are described. Properties and applications of N,N-bis(trifluoromethyl)anilines in syntheses of aromatic compounds containing the (CF3)2N group are presented.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► [ArN2][N(CF3)2] are convenient reagents for introduction of N(CF3)2 group. ► Decomposition of [ArN2][N(CF3)2] in the presence of CuI[WCA]·4 CH3CN salts. ► Properties and applications of Ar-N(CF3)2. ► 4-BrC6H4N(CF3)2 offers a variety of possibilities for further derivatisation. ► Various new (CF3)2N-aromatic compounds.
