| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314784 | Journal of Fluorine Chemistry | 2013 | 4 Pages |
Abstract
A highly efficient and practical approach to the hydrodefluorination of CF bond in fluoroarenes in the presence of 5 mol% NiCl2(PCy3)2 with lithium tri-t-butoxyaluminium hydride (LiAl(O-t-Bu)3H) under mild conditions has been developed.
Graphical abstractA highly efficient and practical NiCl2(PCy3)2-catalyzed hydrodefluorination of CF bond in fluoroarenes with lithium tri-t-butoxyaluminium hydride (LiAl(O-t-Bu)3H) was developed.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The activation of CF bonds. ► The hydrodefluorination of fluoarenes. ► A cheap, easy to handle reducing agent, lithium tri-t-butoxyaluminium hydride (LiAl(O-t-Bu)3H). ► Using 5 mol% NiCl2(PCy3)2 as catalyst.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Juan Xiao, Jingjing Wu, Wenwen Zhao, Song Cao,