| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314794 | Journal of Fluorine Chemistry | 2007 | 4 Pages |
Abstract
Photoirradiation of the pentafluorophenyl-substituted Z-hemithioindigo 1 causes a novel type of photoinduced cyclization, to produce the intramolecularly cyclized alcohol 2 and its dehydrated ether 3. For this photoinduced cyclization, the o-fluorine atoms of the phenyl group of 1 are found to be crucial.
Graphical abstractPhotoirradiation of 1 causes a novel type of photoinduced cyclization, to produce the intramolecularly cyclized alcohol 2 and its dehydrated ether 3, instead of the Z–E isomerized product.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Kiyoshi Tanaka, Kiyoshi Kohayakawa, Takayuki Irie, Satoru Iwata, Kazuto Taguchi,