Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1314795 | Journal of Fluorine Chemistry | 2007 | 6 Pages |
Abstract
1,1-Difluoroethysilanes (R3SiCF2CH3, R = Me or Et) were synthesized from 1,1-difluoroethyl phenyl sulfone and chlorosilanes using magnesium metal via reductive 1,1-difluoroethylation. It was confirmed that 1,1-difluoroethylsilanes were effective 1,1-difluoroethylating reagents for carbonyl compounds.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ryo Mogi, Kazuo Morisaki, Jinbo Hu, G.K. Surya Prakash, George A. Olah,