| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314823 | Journal of Fluorine Chemistry | 2007 | 6 Pages |
Abstract
Under fluoride activation, the vinyl fluorine of perfluoroketene dithioacetal may be substituted by silylated nucleophiles. Using silyl alkynes, a formal transition metal free sila-Sonogashira cross-coupling reaction occurred. The resulting enynes were hydrolyzed giving new polyfunctional trifluoromethyl building blocks.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Tiziano Nocentini, Cédric Brulé, Jean-Philippe Bouillon, Sonia Gouault-Bironneau, Charles Portella,