Article ID Journal Published Year Pages File Type
1314862 Journal of Fluorine Chemistry 2010 4 Pages PDF
Abstract

A polyfluoroalkylation of pyrrole and phenols with freon BrCF2CF2Br using sulfur dioxide-substituted pyridine activating system proceeds at the aromatic nucleus by a free-radical mechanism. The essential influence of the basicity of the medium is demonstrated and discussed.

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Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Activation of free-radical polyfluoroalkylation of organic substrates with freon BrCF2CF2Br using a system of organic base-electron transfer mediator
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