| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314863 | Journal of Fluorine Chemistry | 2010 | 5 Pages |
Abstract
Trifluoromethylcopper and pentafluoroethylcopper are prepared conveniently via the reaction of the solid complex Zn(CF3)Br·2DMF with copper(I) bromide in N,N-dimethylformamide. The reactions of both copper species with 2,4-dinitrochlorobenzene, 4-iodonitrobenzene, 4-nitrobenzyl iodide, 4-bromobenzoic acid ethyl ester, 4-iodobenzoic acid ethyl ester, 2-iodopyridine and 2-iodopyrimidine have been studied. The structure of 2,4-dinitrotrifluoromethylbenzene has been elucidated.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mikhail M. Kremlev, Wieland Tyrra, Aleksej I. Mushta, Dieter Naumann, Yurii L. Yagupolskii,