Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1314874 | Journal of Fluorine Chemistry | 2010 | 4 Pages |
Abstract
Radical transannular cyclizations of the non-conjugated dienes, such as 3,7-dimethylenebicyclo[3.3.1]nonane and norbornadiene with SF5Cl upon UV-irradiation led to the corresponding SF5-substituted 3,7-noradamantane and nortricyclanes with high yields. Radical reaction of cis,cis-1,5-cyclooctadiene with SF5Cl led to a product of SF5Cl addition to one of the diene double bonds either UV-irradiation or triethylborane were used for radical initiation.
Graphical abstractRadical reactions of the non-conjugated cyclic dienes with SF5Cl were described.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Maxim V. Ponomarenko, Yurii A. Serguchev, Gerd-Volker Röschenthaler,