Phase transformations in LnF3–(Ln, Zr)–ZrF4 systems, where Ln = Sm, Eu, Tm, Yb

Phase transformations in LnF3–(Ln, Zr)–ZrF4 systems (where Ln = Sm, Eu, Tm, Yb) in the temperature range 700–900 °C have been investigated by chemical and X-ray phase analyses, UV and IR spectroscopy. Synthesis conditions of nonstoichiometric samarium, europium, ytterbium and thulium fluorides, which are products of interaction between LnF3 and Ln and original substances for the preparation of compounds such as LnZrF6 are given. The crystal lattice of the fluorozirconates obtained is similar to the Yb27F64 superstructure. Thulium fluorozirconate (TmZrF6), whose structure is indexed as the Tm13F32−δ superstructure of hexagonal system, is an exception. For all compounds obtained, the lattice parameters have been calculated and the absorption bands of IR spectra have been interpreted.

Graphical abstractThe investigation of phase transformations in LnF3–(Ln, Zr)–ZrF4 systems (where Ln = Sm, Eu, Tm, Yb) in the temperature range 700–900 °C have been studied. It has been shown that on contact interaction between LnF3 and lanthanide, nonstoichiometric compounds of lanthanides in lower oxidation states, LnF2+x, are formed.Figure optionsDownload full-size imageDownload as PowerPoint slide