| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1314938 | Journal of Fluorine Chemistry | 2008 | 6 Pages |
Abstract
A facile synthetic route to N-polyfluoro(trimethylsilyl)ethyl azole derivatives was developed starting from N-bromo(chloro)polyfluoroethyl-substituted azoles. The silanes thus obtained were reacted with various electrophiles in the presence of the fluoride ion to yield the corresponding fluorinated carbinols, ketones, carboxylic acids, and methyl dithiocarboxylates as well as N-pentafluoroethylbenzimidazole.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Kirill I. Petko, Sergey Y. Kot, Lev M. Yagupolskii,