Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1315020 | Journal of Fluorine Chemistry | 2009 | 5 Pages |
Allylation of 1,3-dicarbonyl compounds with allylic alcohols was successfully accomplished using rare earth metal (III) bis(perfluorooctanesulfonyl)imide [RE(NPf2)3, RE = La∼Lu] as catalysts in fluorous solvents. Ytterbium bis(perfluorooctanesulfonyl)imide [Yb(NPf2)3] catalyzes the high efficient reaction of allylation in fluorous solvents. By simple separation, fluorous phase containing only catalyst can be reused several times.
Graphical abstractAllylation of 1,3-dicarbonyl compounds with allylic alcohols was successfully accomplished using rare earth metal (III) bis(perfluorooctanesulfonyl)imide [RE(NPf2)3, RE = La∼Lu] as catalysts in fluorous solvents. Ytterbium bis(perfluorooctanesulfonyl)imide [Yb(NPf2)3] catalyzes the high efficient reaction of allylation in fluorous solvents. By simple separation, fluorous phase containing only catalyst can be reused several times.Figure optionsDownload full-size imageDownload as PowerPoint slide