Article ID Journal Published Year Pages File Type
1315020 Journal of Fluorine Chemistry 2009 5 Pages PDF
Abstract

Allylation of 1,3-dicarbonyl compounds with allylic alcohols was successfully accomplished using rare earth metal (III) bis(perfluorooctanesulfonyl)imide [RE(NPf2)3, RE = La∼Lu] as catalysts in fluorous solvents. Ytterbium bis(perfluorooctanesulfonyl)imide [Yb(NPf2)3] catalyzes the high efficient reaction of allylation in fluorous solvents. By simple separation, fluorous phase containing only catalyst can be reused several times.

Graphical abstractAllylation of 1,3-dicarbonyl compounds with allylic alcohols was successfully accomplished using rare earth metal (III) bis(perfluorooctanesulfonyl)imide [RE(NPf2)3, RE = La∼Lu] as catalysts in fluorous solvents. Ytterbium bis(perfluorooctanesulfonyl)imide [Yb(NPf2)3] catalyzes the high efficient reaction of allylation in fluorous solvents. By simple separation, fluorous phase containing only catalyst can be reused several times.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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