| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315045 | Journal of Fluorine Chemistry | 2010 | 6 Pages |
Abstract
Monofluoromethyl 3,5-bis(trifluoromethyl)phenyl sulfone 1 was synthesized and employed in Julia–Kocienski fluoroolefination reaction with various ketones and aldehydes. Optimal reaction conditions were found to be the treatment of substrates with KOH or CsF in DMSO at room temperature. Mixtures of (E) and (Z) isomers of monofluoroalkenes 4 were obtained in moderate to excellent yields.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
G.K. Surya Prakash, Anton Shakhmin, Mikhail Zibinsky, Istvan Ledneczki, Sujith Chacko, George A. Olah,