| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315055 | Journal of Fluorine Chemistry | 2010 | 5 Pages |
A terminal palladium (II) fluoride complex (FPNP)PdF (where FPNP is a an anionic fluoro-substituted diarylamido/bis(phosphine) pincer ligand) has been prepared and characterized spectroscopically and structurally. An X-ray diffraction study revealed an approximately square–planar environment about Pd and a short Pd–F bond distance. (FPNP)PdF reacted with silanes containing electron-withdrawing groups on Si by exchange of fluoride with one of the substituents on Si. An analysis of the 19F chemical shifts of both the Pd-bound fluoride and of the fluorines on the backbone of the FPNP ligand is provided.
Graphical abstractA terminal palladium fluoride supported by an FPNP ligand has been synthesized and characterized. This complex possesses an approximately square–planar environment about Pd and a short Pd–F bond. It reacts with silane reagents containing electron-withdrawing groups by exchange of fluorine with a substituent on silicon.Figure optionsDownload full-size imageDownload as PowerPoint slide
