| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315067 | Journal of Fluorine Chemistry | 2008 | 5 Pages |
Abstract
The treatment of silyl enol ethers with fluoroalkyl halides (Rf–X) in the presence of RhCl(PPh3)3 gave α-fluoroalkylated ketones. It seems that a rhodium complex derived from the silyl enol ether and RhCl(PPh3)3 played an important role for the oxidative addition of fluoroalkyl halides and the reductive elimination of the product.
Graphical abstractThe treatment of silyl enol ethers with fluoroalkyl halides (Rf–X) in the presence of RhCl(PPh3)3 gave α-fluoroalkylated ketones.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Kazuyuki Sato, Makoto Higashinagata, Takashi Yuki, Atsushi Tarui, Masaaki Omote, Itsumaro Kumadaki, Akira Ando,