| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315078 | Journal of Fluorine Chemistry | 2012 | 4 Pages |
Selective elemental fluorination in ionic liquids (ILs) will be presented as a new methodology. The tested reagents are organic disulphides and organic iodides. In addition, the stabilities of the ionic liquids [EMIM][(C2F5)3PF3], [BMPL][(C2F5)3PF3], [BMPL][OTf] and [BMPL][B(CN)4] against diluted fluorine (5 vol% in nitrogen) are investigated.
Graphical abstractSelective elemental fluorination in ionic liquids as a new methodology. Tested reagents are organic disulphides and organic iodides. Stabilities of selected ionic liquids against diluted fluorine are investigated.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Selective elemental fluorination of organic disulphides and organic iodides in ionic liquids. ► Stability of selected ionic liquids against 1 equiv. of diluted elemental fluorine. ► Reactivity of phenylsulphur trifluoride in [BMPL][(C2F5)3PF3] with benzyl alcohol and 2-phenyl-1,3-dithiane.
