Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1315126 | Journal of Fluorine Chemistry | 2010 | 6 Pages |
Abstract
Treatment of trifluoromethylated propargylic tosylates with hydroxides in a water-organic biphasic solvent system efficiently led to isomerization to allenyl tosylates or hydration to α-tosyloxy ketones at room temperature, just by selection of appropriate reaction conditions.
Graphical abstractTreatment of trifluoromethylated propargylic tosylates with hydroxides in a water-organic biphasic solvent system efficiently led to isomerization to allenyl tosylates or hydration to α-tosyloxy ketones at room temperature, just by selection of appropriate reaction conditions.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yohsuke Watanabe, Takashi Yamazaki,