Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1315171 | Journal of Fluorine Chemistry | 2007 | 6 Pages |
Abstract
In this report, a simple process for preparing HFC-245fa through the reaction of 1,1,1,3,3-pentachloropropane (PCP) and anhydrous HF via two-step vapor-phase catalytic fluorination is described. The antimony pentafluoride catalyst was supported on inert porous materials to improve the catalytic activity. The resulting process catalyst not only exhibited high catalytic activity and excellent thermo-stability, but also improved the performance of SbF5, in terms of hygroscopicity and corrosion.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Heng-Dao Quan, Hui-E Yang, Masanori Tamura, Akira Sekiya,