| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315265 | Journal of Fluorine Chemistry | 2006 | 9 Pages |
Abstract
Both SF5Cl and SF5Br undergo smooth, high yield addition to alkenes and alkynes under the mild free radical chain reaction conditions of triethylborane initiation at low temperature, although the SF5Br chemistry is somewhat limited by its competing high electrophilic reactivity with electron rich alkenes. The SF5Cl addition reaction is relatively insensitive to a wide variety of non-allylic functionalities.
Graphical abstractBoth SF5Cl and SF5Br undergo smooth, high yield addition to alkenes and alkynes under the mild free radical chain reaction conditions of triethylborane initiation at low temperature. Figure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
William R. Dolbier Jr., Samia Aït-Mohand, Tyler D. Schertz, Tatiana A. Sergeeva, Joseph A. Cradlebaugh, Akira Mitani, Gary L. Gard, Rolf W. Winter, Joseph S. Thrasher,